今天回到这个问题,我想我可能能够弄清楚。我做到了!答案很简单,我觉得自己一年都没有得到它是个傻瓜。
关于我发布的代码的两件事:
- 应该使用- IPAddress.MaptoIPv6(参见 MSDN 链接)而不是我编写的那个更容易出错的愚蠢、人为的循环。
 - 一个。后来我在 .NET 4.0 中工作时意识到,我在示例中使用的便利功能直到 .NET 4.5 才可用。我拼凑的一个快速代码示例在这篇文章的底部,以防其他人被困在早期版本的 .NET 中。 
- 真正的解决方案:需要在调用- client.SetSocketOption(SocketOptionLevel.IPv6, SocketOptionName.IPv6Only, 0);之前调用- client.Connect()。
 
这是我今天为测试它而编写的示例应用程序的完整代码示例。我能够使用 ::1 和 127.0.0.1 作为地址建立连接。请注意,服务器Socket是为 IPv6 创建的,并且该选项在客户端和服务器SocketOptionName.IPv6Only上都设置为 0 。
using System;
using System.Net;
using System.Net.Sockets;
using System.Text;
namespace sixsharp
{
    class Program
    {
        static void Main(string[] args)
        {
            if(args.Length <= 0) //run as server
                RunServer();
            else
                RunClient(args);
            Console.WriteLine("Press enter to close.");
            Console.ReadLine();
        }
        static void RunServer()
        {
            using(Socket serv = new Socket(AddressFamily.InterNetworkV6, SocketType.Stream, ProtocolType.Tcp))
            {
                serv.SetSocketOption(SocketOptionLevel.IPv6, SocketOptionName.IPv6Only, 0);
                serv.Bind(new IPEndPoint(IPAddress.IPv6Any, 1337));
                serv.Listen(5);
                Console.Write("Listening for client connection...");
                using(Socket client = serv.Accept())
                {
                    Console.WriteLine("Client connection accepted from {0}", client.RemoteEndPoint.ToString());
                    byte[] buf = new byte[128];
                    client.Receive(buf, 128, SocketFlags.None);
                    Console.WriteLine("Got \'{0}\' from client", Encoding.ASCII.GetString(buf));
                    Console.WriteLine("Echoing response");
                    client.Send(buf);
                    client.Shutdown(SocketShutdown.Both);
                }
            }
            Console.WriteLine("Done.");
        }
        static void RunClient(string[] args)
        {
            using(Socket client = new Socket(AddressFamily.InterNetworkV6, SocketType.Stream, ProtocolType.Tcp))
            {
                client.SetSocketOption(SocketOptionLevel.IPv6, SocketOptionName.IPv6Only, 0);
                Console.WriteLine("Setting up address, input is {0}", args[0]);
                IPEndPoint ep;
                try
                {
                    ep = new IPEndPoint(IPAddress.Parse(args[0]), 1337);
                }
                catch(FormatException fe)
                {
                    Console.WriteLine("IP address was improperly formatted and not parsed.");
                    Console.WriteLine("Detail: {0}", fe.Message);
                    return;
                }
                if(ep.AddressFamily == AddressFamily.InterNetwork)
                {
                    ep = new IPEndPoint(ep.Address.MapToIPv6(), ep.Port);
                    if(!ep.Address.IsIPv4MappedToIPv6 || ep.Address.AddressFamily != AddressFamily.InterNetworkV6)
                    {
                        Console.WriteLine("Error mapping IPv4 address to IPv6");
                        return;
                    }
                }
                Console.WriteLine("Connecting to server {0} ...", ep.ToString());
                try
                {
                    client.Connect(ep);
                }
                catch(Exception ex)
                {
                    Console.WriteLine("Unable to connect.\n Detail: {0}", ex.Message);
                    return;
                }
                client.Send(Encoding.ASCII.GetBytes("This is a test message. Hello!"));
                byte[] buf = new byte[128];
                client.Receive(buf);
                Console.WriteLine("Got back from server: {0}", Encoding.ASCII.GetString(buf));
                client.Shutdown(SocketShutdown.Both);
            }
            Console.WriteLine("Done.");
        }
    }
}
客户端输出:
  设置地址,输入为 10.2.6.179 
  Connecting to server [::ffff:10.2.6.179]:1337 ...
  从服务器返回:这是一条测试消息。你好!  
  
  完毕。
  按回车关闭。
服务器输出:
  正在侦听客户端连接...从 [::ffff:10.2.6.179]:56275 接受的客户端连接
  得到“这是一条测试消息。你好!
                   ' 来自客户端
  回显响应
  完成。
  按回车关闭。  
提供 .NET 早期版本中缺少的便利功能的示例扩展方法:
static class IPAddressExtensions
{
    public static IPAddress MapToIPv6(this IPAddress addr)
    {
        if(addr.AddressFamily != AddressFamily.InterNetwork)
            throw new ArgumentException("Must pass an IPv4 address to MapToIPv6");
        string ipv4str = addr.ToString();
        return IPAddress.Parse("::ffff:" + ipv4str);
    }
    public static bool IsIPv4MappedToIPv6(this IPAddress addr)
    {
        bool pass1 = addr.AddressFamily == System.Net.Sockets.AddressFamily.InterNetworkV6, pass2;
        try
        {
            pass2 = (addr.ToString().StartsWith("0000:0000:0000:0000:0000:ffff:") ||
                    addr.ToString().StartsWith("0:0:0:0:0:ffff:") ||
                    addr.ToString().StartsWith("::ffff:")) && 
                    IPAddress.Parse(addr.ToString().Substring(addr.ToString().LastIndexOf(":") + 1)).AddressFamily == AddressFamily.InterNetwork;
        }
        catch
        {
            return false;
        }
        return pass1 && pass2;
    }
}