This removes all FullAccess accessrights from a mailbox for a certain user.
Remove-MailboxPermission -identity MyMailbox -user SomeUser -AccessRights FullAccess
This removes SendAs accessrights
Remove-MailboxPermission -identity MyMailbox -user SomeUser -AccessRights SendAs
Is there something I can do to remove ALL accessrights in one go, so I do not have to explicitly have to remove every single kind of accessright?