No, I don't see a way you could do this. You could do the TransactionScope part, but the resolve/call part I just don't see working.
Well, I guess you could get it to work. You'd need a dummy instance of TMyService (or whatever object you're intercepting), and your interception behavior would need to do a bunch of reflection to figure out the type to grab, resolve it, and use reflection again to invoke the specific method. It could be done, but it would be hideously slow.
I'm not going to provide code for this, because I don't think it's a good idea. What scenario are you trying to implement with this - there's probably an easier way to accomplish it.