I recently upgraded Xcode to version 4.4.1, and now, CSS files don't take on the default syntax coloring associated with CSS files. A dash appears next to the "None" option under Editor | Syntax coloring. I have to manually check off the CSS option under Syntax coloring to associate colored syntax with CSS.
A last note: I don't use Xcode as an IDE, I use it as a text editor. All other languages I work in take on syntax coloring without a problem; this issue applies only to CSS.