你想要这样的东西吗?我不完全理解这个问题
string[] fileEntries = Directory.GetFiles("C:\\temp\\").Where(p => 
                                 p.EndsWith(".txt")).ToArray<string>();
foreach (string fileName in fileEntries)
{
    lb.Items.Add(new ListItem(fileName, fileName);
}
好的,所以您的列表框充满了文件名?
private StreamReader sr;
public void OutputBtn_Click(object sender, EventArgs e)
{
    foreach(var li in lb.Items)
    {
        PrintDocument PrintD = new PrintDocument();
        PrintD.PrintPage += new PrintPageEventHandler(this.PrintDocument_PrintPage);
        sr = new StreamReader(li.ToString());
        PrintD.Print();        
    }
}
private void PrintDocument_PrintPage(object sender, PrintPageEventArgs ev) 
{
     float linesPerPage = 0;
     float yPos =  0;
     int count = 0;
     float leftMargin = ev.MarginBounds.Left;
     float topMargin = ev.MarginBounds.Top;
     String line = null;
     // Calculate the number of lines per page.
     linesPerPage = ev.MarginBounds.Height  / 
        printFont.GetHeight(ev.Graphics) ;
     // Iterate over the file, printing each line.
     while (count < linesPerPage && ((line = sr.ReadLine()) != null)) 
     {
        yPos = topMargin + (count * printFont.GetHeight(ev.Graphics));
        ev.Graphics.DrawString (line, printFont, Brushes.Black, 
           leftMargin, yPos, new StringFormat());
        count++;
     }
     // If more lines exist, print another page.
     if (line != null) 
        ev.HasMorePages = true;
     else 
        ev.HasMorePages = false;
}